119.38 : Chemical Specs: Assay (CHCl 3) Min. Chloroform AH049-4 Version 1.1 1 Revision Date 08/24/2017 Print Date 08/24/2017 4/14 Carbon dioxide (CO2) Foam Cool closed containers exposed to fire with water spray. Chloroform CHCl3 Page 1 Section 1: Chemical Product Product Name: Chloroform CAS Number: 67-66-3 EC Number: 212-742-4 UN Number: 1888 Synonym: Trichloromethane, Formyl Trichloride, Methane Trichloride, Methyl Trichloride, Methenyl Trichloride, TCM, Freon 2,Cloroformio , Chloroforme , Хлороформ Chemical Name: Chloroform this information. additional knowledge and experience are gained. View | Download PDF. 2 EU-DSD / DPD Indication(s) of danger and R phrase(s) Highly flammable R11 3.2 Label elements EU-GHS / CLP Hazard pictogram(s)/Symbols. Container may explode in the heat of fire. Incid. Limited evidence of a carcinogenic effect. - Find MSDS or SDS, a COA, data sheets and more information. Belongs to the Following Reactive Group(s). Potassium Iodide is a metal halide composed of potassium and iodide with thyroid protecting and expectorant properties. SECTION 14 - TRANSPORT INFORMATION IATA Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing Group: III IMO Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing Group: III RID/ADR Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing group: III SECTION 15 - REGULATORY INFORMATION European/International Regulations … R40 Limited evidence of a carcinogenic effect. P233 - Keep container tightly closed. Hazard Class and Category Code(s) Flammable liquid Flam. S-phrase(s) S36/37 Wear suitable protective clothing and gloves. Acetone deuterated Hazard symbols. DOT ID & Guide . 2.3 3. Limited evidence of a carcinogenic effect. Symbol: GHS06, GHS08: Signal Word: Danger Hazard Statements: H302-H315-H319-H331-H336-H351-H361d-H372: Precautionary Statements: P261-P281-P305 + P351 + P338-P311 Receptacle form: Thin mouth glass bottle: Hazard symbols: Signal word: Danger: Symbol Mark: The preservation method: Toxicity data: LD50 908mg/kg taking orally Rat CAS 67-66-3, chemical formula CHCl₃. Hazard Symbol 1 Chloroform, ACS Safety Data Sheet WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm - www.P65Warnings.ca.gov 3.1 Other hazards - none This section provides a listing of alternate names for this chemical, CAS No. Hazard symbol(s) R-phrase(s) R22 R38 R40 R48/20/22 Harmful if swallowed. R 40 Limited evidence of a carcinogenic effect. CHLOROFORM: CHLOROFORM: Hazard Class: 6.1: 6.1(9.2) UN Number: UN1888: UN1888: Packing Group: III: III: Section 15 - Regulatory Information US FEDERAL TSCA CAS# 67-66-3 is listed on the TSCA inventory. It is oxidized by strong oxidizers such as chromic acid forming phosgene and chlorine. CAS 67-66-3, chemical formula CHCl₃. Inhalation of vapors can cause headaches, drowsiness, dizziness, and nausea. View information & documentation regarding Chloroform-d, including CAS, MSDS & more. It is intended for informational use by persons having technical skill for GHS06, GHS08. Web site owner: [MCA Case History 1661(1970)]. Safety hazard symbol notice Documentation needs to be consulted in all cases where the symbol is used to find out the nature of the potential hazard and any actions which have to be taken. Powdered aluminum and carbon tetrachloride (also methyl chloride and chloroform or mixtures of these chemicals) exploded when heated (to 153° C) and by impact, [Chem. A clear colorless liquid with a characteristic odor. 17034 Classification. CAS# 64-17-5 is listed on the TSCA inventory. H319 Causes serious eye irritation. Chloroform has been classified as a potential to probable human carcinogen, based on adequate evidence for carcinogenicity in animals. EINECS: This product is on the European Inventory of Existing Commercial Chemical 2298 0 obj <>stream The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. GHS Chloroform Labels (79665) Chloroform: Harmful if inhaled or swallowed. attached gloves, visors, etc. Quality Management Dossier; Operational Excellence Dossier; SDS; CoA; Certificates ; Material Qualification Dossier; Synonyms: TCM, Trichloromethane, Methane trichloride, Methyl trichloride EC Number: 200-663-8 Hill Formula: CHCl₃ CAS #: 67-66-3 Chemical Formula: CHCl₃ … It is a colorless, strong-smelling, dense liquid that is produced on a large scale as a precursor to PTFE. It appears that your browser has JavaScript disabled. Dimethyl sulfoxide deuterated N/A. Used as a solvent, to make other chemicals, as a fumigant. 3.1 Other hazards - none (EPA, 1998), It is classified as moderately toxic. 2290 0 obj <>/Filter/FlateDecode/ID[<3E08AA8C5B703D4DBAA6BD7F37C98C50><0C97D76832D25A4CB15137DFB26BA312>]/Index[2272 27]/Info 2271 0 R/Length 91/Prev 317317/Root 2273 0 R/Size 2299/Type/XRef/W[1 2 1]>>stream All liquid chemicals have been tested between approximately 20°C and It is a human suspected carcinogen. Hence sinks in water. Nonflammable under most conditions, but burns under extreme conditions. Matrix. Conservation & Recovery Act) - U Series Wastes - Acutely Toxic Wastes & Other Hazardous Characteristics waste number U044 (Chloroform) . Chloroform 67-66-3 IBC Code: Category Y Hazard Summary. This material does not contain any Class 1 Ozone depletors. Wear self-contained breathing apparatus and special protective clothing. Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. CAUTION: This information is based upon technical data that Chemical Details: Stabilized : Chemical CAS Number: 67-66-3 : Chemical Formula: CHCl 3: Chemical Formula Weight: F.W. This information is not intended as a license to operate 1 mL. Chloroform Deuterated Hazard symbols. including, without limitation, no warranties of merchantability or fitness Certified Reference Material. Emergency overview Hazards identification Routes of entry Potential acute health effects Toxic by inhalation. HAZARDS … that the garment selected is suitable for the intended use. The Uvasol® solvents range has been specially designed for spectroscopy and other applications requiring solvents of the highest spectral purity. R36/38 Irritating to eyes and skin. May displace oxygen and cause rapid suffocation. Suspected of causing cancer. Chloroform. 2.0 mg/mL in MeOH. Chloroform SARA 313 toxic chemical notification and release reporting: Chloroform CERCLA: Hazardous substances. R 40 Limited evidence of a carcinogenic effect. Certified Secure. The addition will increase the polarity of the solvent and potentially impact certain applications. %%EOF Since conditions of use Ambient (>5 °C) Typical Chromatogram TC. Skin: Wear appropriate personal protective clothing to prevent skin contact. been tested at a concentration of greater than 95% unless otherwise Substance name : Chloroform CAS-No. Will not burn under typical fire conditions. Irritating to skin. H336 May cause drowsiness or dizziness. It is subject to revision as CAS Number. Catalog Number Cat. Other OSHA standards that generally apply to hazardous substances include the Hazard Communication standard and the Respiratory Protection standard . evaluation under their specific end-use conditions, at their own discretion It develops acidity from prolonged exposure to air and light. R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Since addition of acetone to chloroform in the presence of base will result in a highly exothermic reaction, it is thought that a base was in the bottle. –Lead, cadmium, chloroform, tetrachloroethylene and other chlorinated solvents • Effects on the reproductive system –Various pesticides, lead, ethylene oxide • Cancers –Ethylene oxide, benzene, various pesticides, some chlorinated solvents, many cytotoxic agents Health Impacts of Chemical Exposure . Can cause temporary incapacitation or residual injury. If fabric Chloroform can be toxic if inhaled or swallowed. It is the user's responsibility to Irritating to skin. National Ocean Service, Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products): Carbon oxides expected to be the primary hazardous combustion product Special protective equipment and precautions for fire fighters: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Also, it is a central nervous system depressant and a gastrointestinal irritant. Chloroform sc-239527 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Chloroform STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. Slightly soluble in water. : 67-66-3 Product code : LC13040 Formula : CHCl3 Synonyms : 1,1,1-trichloromethane / Chloroform / formyl trichloride / freon 20 / methane trich loride / methane, trichloro- / methenyl chloride / methenyl trichloride / methyl trichloride / R 20 / R 20 Additional Information. Denser (12.3 lb / gal) than water and slightly soluble in water. endstream endobj startxref The laboratory boots required safety symbol indicates when street shoes are not adequate for certain lab-related tasks.… Gases Under Pressure - Compressed gas GHS Label Elements Symbol(s) Signal Word Warning Hazard Statement(s) Contains gas under pressure; may explode if heated. (method A and B) or ASTM D6978 test methods. under or a recommendation to infringe any patent or technical information COVID-19 is an emerging, rapidly evolving situation. Hazard identification Highly flammabl e. May form explosive peroxides. Related Pages. Exposure to chloroform may also cause cancer. : Chloroform: 10 lbs. Normalized breakthrough times H319 Causes serious eye irritation. CAS# 25377-72-4 is listed on the TSCA inventory. Formula and structure: Chloroform chemical formula is CHCl 3 and its molar mass is 119.37 g mol-1. Explosive Material Hazard. This material contains Chloroform (CAS# 67-66-3, 99+%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 Chloroform also has minor applications as a process solvent in the production of some pharmaceuticals and agricultural products. Chloroform is use as a solvent for fats, oils, rubber, alkaloids, waxes, gutta-percha, resins; as cleansing agent; in fire extinguishers to lower the freezing temperature of carbon tetrachloride. Explosive material hazard – It pertains to chemicals in the lab that has … … It is practically not flammable at lower temperatures. Additional UPS-imposed hazardous material charge. P240 - Ground/bond container and receiving equipment. Dermal contact. Due to its light sensitivity, it may undergo degradation with time. Chloroform-D | CHCl3 | CID 71583 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. chemicals, such as strong acids, and should not be worn when 2 Serious eye Irritation Eye Irrit. chloroform structure. Chloroform, also known by the IUPAC name of trichloromethane, is an organic solvent very used in chemical and pharmaceutical industries. h��V]k�0�+z�:ɒ%�P Chloroform CAS 67-66-3 EMPROVE® ESSENTIAL - Find MSDS or SDS, a COA, data sheets and more information. Due to chloroform’s volatility, inhalation is the principal hazard, but the liquid is also toxic if An inadequately cooled addition of sodium to a chloroform-methanol mixture (sodium methoxide) caused a violent explosion, [MCA Case History No. When freeze-dried brain was extracted at -4-0 °C with dry chloroform methanol (2:1, v/v), four of the five enzymes examined were recovered in the diethyl ether-waresidue without inactivation. Eng. Signs and Symptoms of Chloroform Exposure: Signs and symptoms of acute exposure to chloroform vapor may include conjunctivitis and blepharospasm (twitching of the eyelid). Page 2 of 11 Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. It is one of the four chloromethanes and a trihalomethane.It is a powerful anesthetic, euphoriant, anxiolytic and sedative when inhaled or ingested. 67-66-3. Shipping Name: COMPRESSED GAS, N.O.S. Research 34 (1945), ASESB Pot. 3 Effective date : 01.06.2015 Page 1 of 7 Sodium Hydroxide,10.0N Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com performance of fabrics, not complete garments, under controlled conditions. Chloroform GR for analysis (for determinations with dithizone). Unless otherwise stated, permeation was measured for single chemicals. , ( Contains: Nitrogen , Chloroform ) Hazard Class: 2.2 UN#: UN1956 Required Label(s): 2.2 International Bulk Chemical Code This material contains one or more of the following chemicals required by the IBC Code to be identified as dangerous chemicals in bulk. Clean Air Act: CAS# 67-66-3 is listed as a hazardous air pollutant (HAP). rates than the fabric. Concentration Conc. Hazard Symbols:-----Risk Phrases: 24/25 34 CAS#: 108-95-2 Chemical Name: Phenol %: 45-55% EINECS#: 203-632-7 Hazard Symbols: T ... N.O.S. Anyone intending to use this information should first verify 2.3 3. Eye contact. 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